Preheat oven to 350 degrees
Lightly mist tube pan with vegetable oil spray. Dust with flour. Set aside.
Place 2 tablespoons of the cake mix, chocolate chips and pecans in small bowl. Mix and set aside.
Place remaining cake mix, pudding mix, sour cream, oil, water, eggs and vanilla extract in a large mixing bowl.
Blend with an electric mixer on low speed for 1 minute. Scrape down sides of bowl with a rubber spatula.
Increase speed to medium and beat 2 to 3 minutes more scraping sides down as needed. The batter should be thick and well blended.
Fold in the chocolate chip and pecan mixture until it is well distributed.
Pour batter into the pan, smoothing the top. Place on center rack in oven.
Bake the cake until it springs back when lightly pressed with your finger and starts to pull away from sides of the pan. 50 to 55 minutes.
Remove from oven and let it cool on a wire rack for 15 minutes.
Run a long, sharp knife around the edge of the cake and invert onto a cooling rack then invert again onto a serving platter to finish cooling. 20 minutes.